Potassium perrhenate

Potassium perrhenate
Identifiers
CAS Number
  • 10466-65-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 2894851
ECHA InfoCard 100.030.854 Edit this at Wikidata
EC Number
  • 233-953-8
PubChem CID
  • 3661560
InChI
  • InChI=1S/K.4O.Re/q+1;;;;-1;
    Key: QFKRWIFGDGKWLM-UHFFFAOYSA-N
  • [K+].[O-][Re](=O)(=O)=O
Properties
Chemical formula
KO4Re
Molar mass 289.301 g·mol−1
Appearance white solid[1]
Density 5.39 g·cm−3[1]
Melting point 555[2] °C (1,031 °F; 828 K)
Boiling point 1,370[2] °C (2,500 °F; 1,640 K)
Solubility in water
11.9 g·l−1[3]
Refractive index (nD)
1.643 (20 °C)[4]
Hazards
GHS labelling:[5]
Pictograms
GHS03: OxidizingGHS07: Exclamation mark
Warning
Hazard statements
H272, H315, H319, H335
Precautionary statements
P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Potassium perrhenate is an inorganic compound with the chemical formula KReO4.

Preparation

Potassium perrhenate can be produced by the neutralization of potassium hydroxide and perrhenic acid.[2]

K O H + H R e O 4 K R e O 4 + H 2 O {\displaystyle \mathrm {KOH+HReO_{4}\longrightarrow KReO_{4}+H_{2}O} }

Properties

Potassium perrhenate is a white solid that is sparingly soluble in water and ethanol. It have a tetragonal crystal system with the space group I41/a (No. 88), and lattice constants a = 567.4 pm and c = 1266.8 pm.[2] It is a strong oxidizer.[4]

References

  1. ^ a b Sigma-Aldrich Co., product no. 229822.
  2. ^ a b c d hrsg. von Georg Brauer. Unter Mitarb. von M. Baudler (1981). Handbuch der präparativen anorganischen Chemie / 3 (in German). Stuttgart: Enke. p. 1633. ISBN 3-432-87823-0. OCLC 310719495.
  3. ^ Hölemann, Hans; Klesse, Walter (1938-04-22). "Beiträge zur Chemie und Elektrochemie des Rheniums VI. Die Löslichkeit des Kaliumperrhenats in Wasser zwischen 10 und 518°". Zeitschrift für anorganische und allgemeine Chemie. 237 (2). Wiley: 172–176. doi:10.1002/zaac.19382370207. ISSN 0863-1786.
  4. ^ a b Potassium perrhenate, 99% (metals basis), Re 64% at AlfaAesar, accessed on 2013-08-05 (PDF) (JavaScript required).[dead link]
  5. ^ "Potassium perrhenate". pubchem.ncbi.nlm.nih.gov.
  • v
  • t
  • e
H, (pseudo)halogens
chalcogens
  • K2O
  • KOH
  • K2O2
  • KO2
  • KO3
  • K2S
  • KHS
  • K2SO3
  • KHSO3
  • K2SO4
  • KHSO4
  • KHSO5
  • K2S2O3
  • K2S2O5
  • K2S2O7
  • K2S2O8
  • K2Se
  • K2SeO3
  • K2SeO4
  • K2Te
  • K2TeO3
  • K2TeO4
  • K2Po
pnictogens
  • K3N
  • KNH2
  • KN3
  • KNO2
  • KNO3
  • K3P
  • KH2PO3
  • K3PO4
  • K2HPO4
  • KH2PO4
  • KPF6
  • KAsO2
  • K3AsO4
  • K2HAsO4
  • KH2AsO4
B, C group
  • B4K2O7
  • K2CO3
  • KHCO3
  • K2SiO3
  • K2SiF6
  • K2Al2O4
  • K2Al2B2O7
transition metals
  • K2PtCl4
  • K2Pt(CN)4
  • K2TiF6
  • K2PtCl6
  • K2ReCl6
  • KAsF6
  • K2ZrF6
  • K4Fe(CN)6
  • K3Fe(CN)6
  • K3Fe(C2O4)3
  • K2FeO4
  • K2MnO4
  • KMnO4
  • K3CrO4
  • K2CrO4
  • K3CrO8
  • KCrO3Cl
  • K2Cr2O7
  • K2Cr3O10
  • K2Cr4O13
  • K4Mo2Cl8
organic
  • KHCO2
  • KCH3CO2
  • KCF3CO2
  • K2C2O4
  • KHC2O4
  • KC12H23O2
  • KC18H35O2
  • C3H2K2O4
  • C4H6KO4
  • C5H7KO4
  • v
  • t
  • e
Rhenium(0)
Organorhenium(0)
  • Re2(CO)10
Rhenium(I)
Organorhenium(I)
  • Re(CO)5Br
  • ReH(CO)5
Rhenium(II)
  • ReB2
Rhenium(III)
  • Re3Cl9 ("ReCl3")
  • ReBr3
  • ReI
    3
  • K2Re2Cl8
Rhenium(IV)
  • ReO2
  • ReS2
  • ReSe2
  • ReTe2
  • ReCl4
  • ReF
    4
  • ReI
    4
  • K
    2
    ReCl
    6
Rhenium(V)
  • ReCl5
  • ReF5
Rhenium(VI)
  • ReOCl3(P(C6H5)3)2
  • ReF6
  • ReO3
  • ReCl6
Rhenium(VII)
  • ReF7
  • Re2O7
  • Re2S7
  • ReO2F3
  • ReO3Cl
  • ReO3F
  • ReO3NO3
  • K2ReH9
Perrhenates
  • Re2O7(OH2)2
  • NH4ReO4
  • NaReO4
  • AgReO4
  • Organorhenium(VII)
    • CH3ReO3
    • v
    • t
    • e
    Salts and covalent derivatives of the perrhenate ion
    Re2O7(H2O)2 He
    Li Be B C NH4ReO4 O F Ne
    NaReO4 Mg Al(ReO4)3 Si P S Cl Ar
    KReO4 Ca Sc(ReO4)3 Ti V Cr(ReO4)3 Mn Fe(ReO4)2
    Fe(ReO4)3
    Co(ReO4)2 Ni(ReO4)2 Cu Zn Ga(ReO4)3 Ge As Se Br Kr
    Rb Sr Y Zr Nb Mo Tc Ru Rh Pd AgReO4 Cd In Sn Sb Te I Xe
    Cs Ba(ReO4)2 * Lu Hf Ta W ReO4- Os Ir Pt Au Hg Tl Pb Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(ReO4)3 Ce Pr Nd(ReO4)3 Pm Sm Eu Gd(ReO4)3 Tb Dy Ho Er Tm Yb
    ** Ac Th Pa UO2(ReO4)2 Np Pu Am Cm Bk Cf Es Fm Md No